The work function of a substance is \( 3.0 \, \text{eV} \). The longest wavelength of light that can cause the emission of photoelectrons from this substance is approximately.
\( 400 \, \text{nm} \)
\( 200 \, \text{nm} \)
\( 414 \, \text{nm} \)
\( 215 \, \text{nm} \)