Let in a series of \( 2n \) observations, half of them are equal to \( a \) and remaining half are equal to \( -a \). Also by adding a constant \( b \) in each of these observations, the mean and standard deviation of new set becomes \( 5 \) and \( 20 \), respectively. Then the value of \( a^2 + b^2 \) is equal to: