The values of \( a \) and \( b \) for which the system of equations\( 2x+3y+6z=8 \)\( x+2y+az=5 \)\( 3x+5y+9z=b \)has no solution, are:
\( a=3,\ b=13 \)
\( a\neq 3,\ b=3 \)
\( a=3,\ b\neq 13 \)
\( a\neq 3,\ b\neq 13 \)