Which of the following binary mixture does not show the behaviour of minimum boiling azeotropes?
\( \mathrm{C_6H_5OH} + \mathrm{C_6H_5NH_2} \)
\( \mathrm{CS_2} + \mathrm{CH_3COCH_3} \)
\( \mathrm{H_2O} + \mathrm{CH_3COC_2H_5} \)
\( \mathrm{CH_3OH} + \mathrm{CHCl_3} \)