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Consider the above reactions, the product \( \mathrm{A} \) and product \( \mathrm{B} \) respectively are:

Among the following structures, which will show the most stable enamine formation? (Where Me is \( \mathrm{-CH_3} \))

The correct stability order of the following diazonium salt is

Given below are two statements:
Statement -I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl of the amide to the nitrogen atom.
Statement -II : The group is migrated in Hofmann degradation reaction to electron deficient atom.

An organic compound ‘A’ on reaction with \( \mathrm{NH_3} \) followed by heating gives compound B. Which on further strong heating gives compound C \( \mathrm{(C_8H_5NO_2)} \). Compound C on sequential reaction with ethanolic \( \mathrm{KOH} \), alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A is:

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A: Aniline on nitration yields ortho, meta & para nitro derivatives of aniline
Reason R : Nitrating mixture is a strong acidic mixture
In the light of the above statements, choose the correct answer from the options given below.

. Match List -I with List-II

Choose the correct answer from the options given below:

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): Experimental reaction of \( \mathrm{CH_3Cl} \) with aniline and anhydrous \( \mathrm{AlCl_3} \) does not give o and p-methylaniline.
Reason (R): The \( -\mathrm{NH_2} \) group of aniline becomes deactivating because of salt formation with anhydrous \( \mathrm{AlCl_3} \) and hence yields m-methyl aniline as the product.
In the light of the above statements, choose the most appropriate answer from the options given below:

The Hinsberg reagent is:

10.

Identify the major product formed in the following sequence of reactions:

11.

Which among the following represent reagent ‘A’?

12.

An organic compound ‘A’ contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound ‘A’ with standard base indicates that the molecular weight of ‘A’ is \(131 \pm 2\). When a sample of ‘A’ is treated with aq. \( \mathrm{NaOH} \), a liquid separate which contains \( \text{N} \) but not \( \text{Cl} \). Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound ‘A’ is:

13.

Consider the following reaction sequence:

The product B is:

14.

Which statement is NOT correct for p-toluenesulphonyl chloride?

15.

In Friedel-Crafts alkylation of aniline, one gets

16.

Match List – I with List – II:

List – I	List – II
(a) Benzenesulphonyl chloride	(i) Test for primary amines
(b) Hoffmann bromamide reaction	(ii) Anti Saytzeff
(c) Cabylamine reaction	(iii) Hinsberg reagent
(d) Hoffmann orientation	(iv) Known reaction of Isocyanates

Choose the correct answer from the options given below:

17.

The correct sequential order of the reagents for the given reaction is

18.

The reaction of with bromine and \( \mathrm{KOH} \) gives \( \mathrm{RNH_2} \) as the end product. Which one of the following is the intermediate product formed in this reaction?

19.

A primary aliphatic amine on reaction with nitrous acid in cold \( 273 \, \mathrm{K} \) and there after raising temperature of reaction mixture to room temperature \( 298 \, \mathrm{K} \), gives a/an:

20.

With respect to the following reaction, consider the given statements:

(a) o-Nitroaniline and p-nitroaniline are the predominant products
(b) p-Nitroaniline and m-nitroaniline are the predominant products
(c) \( \mathrm{HNO_3} \) acts as an acid
(d) \( \mathrm{H_2SO_4} \) acts as an acid

21.

The final product ‘C’ in the following series of reactions:

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JEE Main 2022 29th June Evening Shift

In Friedel-Crafts alkylation of aniline, one gets

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JEE Mains JEE Advance BITSAT
JEE Mains | PYQ