One of the by-products formed during the recovery of \( \mathrm{NH_3} \) from Solvay process is :
\( \mathrm{CaCl_2} \)
\( \mathrm{Ca(OH)_2} \)
\( \mathrm{NaHCO_3} \)
\( \mathrm{NH_4Cl} \)