
Two vessels \( A \) and \( B \) are connected via stopcock. The vessel \( A \) is filled with a gas at a certain pressure. The entire assembly is immersed in water and is allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel \( A \) expands into vessel \( B \) and no change in temperature is observed in the thermometer. Which of the following statement is true?
The effect of temperature on spontaneity of reactions are represented as:
| \( \Delta H \) | \( \Delta S \) | Temperature | Spontaneity |
|---|---|---|---|
| (A) \( + \) | \( - \) | any \( T \) | Non spontaneous |
| (B) \( + \) | \( + \) | low \( T \) | Spontaneous |
| (C) \( - \) | \( - \) | low \( T \) | Non spontaneous |
| (D) \( - \) | \( + \) | any \( T \) | Spontaneous |
The incorrect combinations are:
